Preheat your oven to 425°F (220°C).
In a large mixing bowl, whisk together the olive oil, Parmesan cheese, garlic powder, smoked paprika, dried oregano, dried thyme, sea salt, and black pepper until well combined.
Add the potato wedges to the bowl and toss thoroughly to ensure each piece is evenly coated with the herb and cheese mixture.
Line a baking sheet with parchment paper and arrange the seasoned potato wedges in a single layer, skin side down, ensuring they are spaced apart for optimal crispiness.
Bake in the preheated oven for 35–40 minutes, or until the potatoes are tender on the inside and have developed a deep golden-brown, crispy crust on the outside.
Remove from the oven and let them rest for 5 minutes to allow the Parmesan crust to set.
Transfer the wedges to a serving platter, sprinkle with finely chopped fresh chives, and serve immediately.